Each cell is made of two parallel lead plates (electrodes), one coated with lead dioxide (PbO2 ) and a solution of sulfuric acid electrolyte. Separators between the electrodes eliminate the possibility of electrical short between the electrodes.
During discharging the electrochemical energy stored in the electrodes is converted to electrical energy. The electrochemical reactions in the battery during discharging, results in water and Lead Sulfate which coats both electrodes, recharging restores the situation.
While charging electrolysis of water decomposes, as a byproduct, water to its ingredients. Oxygen gas is formed at the positive plate and Hydrogen gas at the negative plate.
Flooded Lead Acid Batteries
In flooded Batteries, also called Wet Lead Acid batteries, or Conventional Lead Acid Batteries, the oxygen and hydrogen gases formed during charging are vented to the air. The batteries therefore require periodic maintenance, performed by authorized personnel, in order to check the sate of the battery and refill the missing water, if needed. Due to hydrogen’s explosive nature the batteries should be located in separate unmanned and well vented rooms. These batteries are generally used for UPS applications, only in large installations, where long life and cost /performance predominate, and where maintenance personnel is available.
Sealed Lead Acid Battery (SLA Batteries)
In a Sealed Lead Acid Battery the possibility of gas venting to the air is eliminated. The oxygen diffuses through the separator from the positive plate to the negative plate, where it is recombined with the hydrogen to form water. These batteries do not require water refilling and are therefore called also Free Maintenance Batteries.
To enable the possibility of pressure relief in the battery, mainly during overcharging, the batteries are generally equipped with relief valves, regulated to preset pressure level. These batteries are therefore called Valve Regulated Lead Acid (VRLA) Batteries.
SLA batteries are considered dry type, generally spill proof and leak proof even in case of container cracks or fractures. They can be located within the UPS as any other electrical component.
Following features of the SLA Battery cause UPS manufactures’ to prefer VRLA technology for UPS Battery applications:
Maintenance free, no water topping up is required during the whole service life of the battery. No battery equalization charge is normally required.
Non hazardous, have no restrictions for rail, road, sea or air transportation as part of the UPS or as separate items.
Rugged and vibration resistant. Can be shipped via parcel post or fast shipping service.
Non corrosive can be used for marine applications or wet environment.
Can be located in any position (horizontal or vertical), enabling flexibility in UPS design and battery location.
Batteries can be located adjacent to each other or on top of each other (provided that weight and venting are considered). Compact packaging in the UPS enables using UPS internal batteries while increasing capacity and backup time.
About 99% of the gasses are recombined within the battery; practically no hydrogen is emitted to the air. The batteries can be located in manned locations, where normal venting exists.
The UPS can be designed to allow replacement or hot swapping of failed batteries by the operators, or by local service people.
High rate discharge ability. As requested for UPS systems that generally provide high energies for relatively short times.
No memory effect. VRLA batteries retain their full charge in float condition during battery lifetime.